You don't mention a bathroom, I assume this has one, else this thread will take on a new direction as it would not be an ADU.
Yes, you can use a detached ADU. It is the functionality and market acceptance, not the location, which matters.
Local codes may prohibit an attached ADU, so yes, that needs investigated too. Now that said, IF there used to be access to that area from the interior, or it could be easily put back (say by taking down one piece of sheetrock on both ends of a hidden staircase), then that changes things too. Simply having a basement with a kitchen, bathroom, and extra bedroom does not make an ADU. I have seen the stairwells blocked (but easily recovered). Just another piece of the puzzle to solve. It is uncommon (in my market at least) to have a finished area like that with no entry from the main dwelling, unless its intent from the beginning was being a duplex.
Are there separate utilities/driveway? Does it LOOK like a 2 unit dwelling? Would someone walking around the building think it was one or two units?
Are you a trainee? Or do you otherwise have a supervisor/mentor? They could assist in HABU analysis, which typically is done early on in the process. Pretty involved to get much assistance on a forum with that. One cannot value a property without knowing its HABU. Zoning, market needs, surrounding uses all come into play. Because once you determine WHAT to call this space, then it has to be valued, which is where HABU is your good friend. If its an illegal addition for instance, with no chance of variance or grandfathering, that obviously impacts value significantly. Problem with that is you then inadvertently become the zoning police and you may or may not want to do that to the borrower. Because if its illegal, it would have to be removed. But only if zoning knows about it. I usually only give an area or street name when I get answers to those types of questions. I don't get paid by the city to be their enforcement officers.
Good luck.